Name | Purity of Diquat |
Synonyms | Aquacide Ccris 8141 Purity of Diquat Deiquat Monohydrat Diquat dibromide monohydrate 1,1'-ethylene-2,2'-bipyridydibromide |
CAS | 6385-62-2 |
EINECS | 626-433-0 |
Molecular Formula | C12H14BrN2O+ |
Molar Mass | 282.16 |
Melting Point | <3200(dec) |
Appearance | neat |
Merck | 13,3386 |
BRN | 3769318 |
Storage Condition | 2~8°C |
MDL | MFCD00211319 |
Physical and Chemical Properties | Chemical properties of dibromo dibromide dihydrate in the form of a single compound, white to yellow crystals. Above 300 deg c decomposition, vapor pressure 13.3 x 10-6pa. Slightly soluble in ethanol and other solvents with hydroxyl groups, insoluble in non-polar organic solvents. The solubility in water at 20 °c was 700g/L. Stable in acidic and neutral solutions, unstable in alkaline conditions. |
Use | Non-selective contact herbicide, slightly conductive. After being absorbed by green plants, the electron transfer of photosynthesis is inhibited, and the reduced bipyridine compound is rapidly oxidized in the presence of oxygen under light induction to form active hydrogen peroxide, the accumulation of this material makes the plant cell membrane damage, the drug receiving parts of the yellow. Suitable for broad-leaved weeds dominant plots of weed control; Can also be used as seed plant drying agent; Can also be used for potato, cotton, soybean, corn, sorghum, flax, sunflower and other crops; when dealing with mature crops, the residual green part and weeds quickly dry, early harvest, seed loss is less; Can also be used as an inhibitor of sugarcane inflorescence formation. Because of the inability to penetrate the mature bark, there is no damage to the underground pole stem. For the promotion of crops dry, the amount of 3~6G active ingredients/100. For farmland herbicidal, no-tillage herbicidal amount of summer maize is 4.5~6G active ingredient/100, Orchard is 6~9 active ingredient/100. Do not directly spray the young trees of crops, because of exposure to the green part of the crop will produce damage. Buneimen Chemical Company of the United Kingdom has been allowed to use Linon 20% water agent to carry out the wheat leaf-drying test in China. |
Risk Codes | R21 - Harmful in contact with skin R25 - Toxic if swallowed R36/37/38 - Irritating to eyes, respiratory system and skin. R48/23/24/25 - R28 - Very Toxic if swallowed R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R48/25 - R43 - May cause sensitization by skin contact R26 - Very Toxic by inhalation R22 - Harmful if swallowed |
Safety Description | S36/37 - Wear suitable protective clothing and gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S60 - This material and its container must be disposed of as hazardous waste. S28 - After contact with skin, wash immediately with plenty of soap-suds. |
UN IDs | UN 2811 |
WGK Germany | 3 |
RTECS | JM5720000 |
Toxicity | LD50 in male, female rats (mg/kg): 147, 121 orally; in male rats (mg/kg): 433 dermally (Gaines, Linder) |
Raw Materials | 1,2-Dibromoethane |
toxicity
Acute Oral ld50231 mg/kg in rats, 125mg/kg in mice, and acute percutaneous ld5050-100 mg/kg in rats. Rabbit> 400mg/kg. Moderate irritation to the skin and eyes. The non-effective dose of the 2-year feeding test for dogs was 1.7mg/kg on the first day, and the non-effective dose of the 3-generation breeding test for rats was 25mg/kg per day, carcinogenic and mutagenic effects. Carp lc5040 mg/L(48h), rainbow trout 45mg/L (24h). Partridge acute oral LD50270mg/kg. Low toxicity to bees.
biological activity
Diquat dibromid hydrate is a Diazine-like herbicide containing two nitrogen atoms.
production method
The fast Dibromo salt of Diptera was synthesized by oxidative coupling of pyridine in the presence of nickel catalyst and then reaction with 1, 2-dibromoethane.